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The hydroxylation of C–H bonds can be carried out by the high-valent Co^III,IV₂(µ-O)₂complex2asupported by the tetradentate tris(2-pyridylmethyl)amine ligand via a Co^III₂(µ-O)(µ-OH) intermediate (3a). Complex3acan be independently generated either by H-atom transfer (HAT) in the reaction of2awith phenols as the H-atom donor or protonation of its conjugate base, the Co^III₂(µ-O)₂complex1a. Resonance Raman spectra of these three complexes reveal oxygen-isotope-sensitive vibrations at 560 to 590 cm⁻¹associated with the symmetric Co–O–Co stretching mode of the Co₂O₂diamond core. Together with a Co•••Co distance of 2.78(2) Å previously identified for1aand2aby Extended X-ray Absorption Fine Structure (EXAFS) analysis, these results provide solid evidence for their “diamond core” structural assignments. The independent generation of3aallows us to investigate HAT reactions of2awith phenols in detail, measure the redox potential and pK_aof the system, and calculate the O–H bond strength (D_O–H) of3ato shed light on the C–H bond activation reactivity of2a. Complex3ais found to be able to transfer its hydroxyl ligand onto the trityl radical to form the hydroxylated product, representing a direct experimental observation of such a reaction by a dinuclear cobalt complex. Surprisingly, reactivity comparisons reveal2ato be 10⁶-fold more reactive in oxidizing hydrocarbon C–H bonds than corresponding Fe^III,IV₂(µ-O)₂and Mn^III,IV₂(µ-O)₂analogs, an unexpected outcome that raises the prospects for using Co^III,IV₂(µ-O)₂species to oxidize alkane C–H bonds. 

Alkylation of d - or l -phenylalanine or valine alkyl esters was carried out using methyl or phenyl Grignard reagents. Subsequent condensation with salicylaldehyde, 3,5-di- tert -butylsalicylaldehyde, or 5-fluorosalicylaldehyde formed tridentate, X 2 L type, Schiff base ligands. Chiral shift NMR confirmed retention of stereochemistry during synthesis. X-ray crystal structures of four of the ligands show either inter- or intramolecular hydrogen bonding interactions. The ligands coordinate to the titanium reagents Ti(NMe 2 ) 4 or TiCl(NMe 2 ) 3 by protonolysis and displacement of two equivalents of HNMe 2 . The crystal structure of one example of Ti(X 2 L)Cl(NMe 2 ) was determined and the complex has a distorted square pyramidal geometry with an axial NMe 2 ligand. The bis-dimethylamide complexes are active catalysts for the ring closing hydroamination of di- and trisubstituted aminoallenes. The reaction of hepta-4,5-dienylamine at 135 °C with 5 mol% catalyst gives a mixture of 6-ethyl-2,3,4,5-tetrahydropyridine (40–72%) and both Z - and E -2-propenyl-pyrrolidine (25–52%). The ring closing reaction of 6-methyl-hepta-4,5-dienylamine at 135 °C with 5 mol% catalyst gives exclusively 2-(2-methyl-propenyl)-pyrrolidine. The pyrrolidine products are obtained with enantiomeric excesses up to 17%.